The longest non-technical word is
floccinaucinihilipilification at 29 letters. Consisting of a series of Latin words meaning "nothing" and defined as "the act of estimating something as worthless," its usage has been recorded as far back as 1741.
[2][3][4] In recent times its usage has been recorded in the proceedings of the United States Senate by Senator
Robert Byrd [5], and at the White House by
Bill Clinton's press secretary
Mike McCurry, albeit sarcastically.